Reports

Plutonium Watch: Separated Inventories of Civil Plutonium Continue to Grow

by David Albright and Lauren Barbour

May 1, 1999

Plutonium is a key ingredient in nuclear weapons, making it one of the most dangerous materials in existence. At the end of 1998, there were over 1,350 tonnes (metric tons) of plutonium in the world, or enough for more than 170,000 nuclear weapons. Most of this plutonium - about 1,115 tonnes of it - was produced in civil nuclear power programs in 32 countries (excluding the breeder reactor in Kazakhstan). The estimated amounts of civil plutonium at the end of 1997 and 1998, shown in Table 1, indicate an annual increase of 65 tonnes.

The amount of plutonium discharged annually is expected to decrease in coming years as recycled civil plutonium is fabricated into mixed-oxide (“MOX”) fuel and irradiated. Enriched uranium fuel is also being irradiated longer, which leads to less plutonium discharged from power reactors.

Civil plutonium is in two basic forms–in spent (irradiated) fuel, or in separated (unirradiated) form. Unirradiated plutonium may be in pure form, in the process of being fabricated into MOX fuel, or in fresh MOX fuel. Once it has been irradiated, however, the plutonium in MOX fuel, like the plutonium produced when uranium fuel is irradiated, is contained in spent fuel. The plutonium in spent fuel is considered more proliferation resistant, because it is difficult to separate the plutonium from the other constituents of spent fuel.

Table 1 shows how much of the world’s civil plutonium is contained in spent fuel and how much is in unirradiated forms. The amount of plutonium in both categories is increasing; roughly 80 percent is in spent fuel.

Table 2 shows the amounts of separated plutonium held by 12 key countries at the end of 1996 and 1997. Most of the figures come from the official public declarations those countries made to the International Atomic Energy Agency (IAEA). Several of the entries in the table are estimates, however, because some declarations are incomplete or ambiguous. In addition, India, Italy and the Netherlands have not made similar declarations of their separated plutonium to the IAEA. Most declarations for 1998 are not yet available; ISIS estimates for 1998 are used in Table 1.

Between 20 and 25 tonnes of plutonium are separated from spent fuel each year, and about 10 tonnes of separated plutonium are fabricated into MOX for use as fuel in light-water reactors. But the fabrication of MOX fuel and its use have not kept pace with the rate of plutonium separation, so the amount of separated plutonium continues to grow. This trend is expected to continue for several more years.

Europe’s MOX fabrication capacity is growing, as are the number of power reactors licensed to use MOX. As a result, civil stockpiles of separated plutonium are expected to begin decreasing some time in the early 2000s.

The rate of decrease is difficult to predict. However, even if the commercial separation of plutonium decreases in Britain and France, as expected, and even if Britain opens its already completed commercial-size MOX fabrication facility, the amount of separated plutonium could still be about 150 tonnes by 2010-2015. This is a rough estimate, but it shows that disposing of large amounts of plutonium will be time consuming. It might be disposed of more rapidly if it were immobilized with high-level waste, an option the United States is pursuing to dispose of some of its excess military plutonium.

The world’s militaries have significantly less plutonium than civil owners do - some 250 tonnes, or about a quarter of the amount in civil inventories. But more than 90 percent of military plutonium is in separated form - and thus more readily usable in weapons. About 100 tonnes of the military plutonium have been declared excess to military needs by Britain, Russia and the United States.

Table A1 shows ISIS estimates of cumulative plutonium production by country at the end of 1998. The figures were calculated using the methodology described in David Albright, Frans Berkhout, and William Walker’s book, Plutonium and Highly Enriched Uranium 1996. Breeder reactors are not included in these estimates. ISIS judges that, without detailed knowledge of plutonium discharges at individual reactors, its estimates by country are uncertain by 10-20 percent, a value greater than that assigned in the book. Uncertainty could not be lowered to less than 5 percent unless each country provided more information about the amount of plutonium discharged in spent fuel, or more information about spent fuel discharges and fuel burnup.

The values in Table A1 are known to be overestimates, because they do not account for the increasing use of recycled plutonium fuel or the relatively rapid radioactive decay of plutonium 241, one of the plutonium isotopes found in civil plutonium. (The other principal isotopes are plutonium 239, plutonium 240, and plutonium 242, all of which have considerably longer half lives than plutonium 241.)

Table A2 corrects for these two cases, at least in the total civil plutonium estimates. Sufficient information is not available to correct each country’s plutonium inventory.
***

Table 1: Estimated Civil Plutonium Inventory (in tonnes)(a)

End of 1997End of 1998
Plutonium Produced (b)1,0501,115
Plutonium in irradiated fuel (c)868920
Plutonium in unirradiated forms182195

BACK

(a) Uncertainties in the amount of plutonium produced are about 10 percent. The uncertainty in the amount of unirradiated plutonium should be less than five percent, because most of these values are declared officially, and stated to be accurate to within 100 kilograms. However, the declarations do not state whether plutonium 241 decay has been accounted for, which could be significant in the case of old separated plutonium.
(b) See Table A2, values rounded.
(c) The values for plutonium in irradiated (spent) fuel have not been rounded, in order to maintain consistency with the quantities of separated plutonium. The uncertainty in the irradiated values is at least 10 percent, and thus they are more approximate than they appear.

Table 2: Key Unirradiated Civil Plutonium Inventories

Separated Civil Plutonium 1996 (in tonnes) (a)

A: Holdings
in-country
B: Holdings in
other countries
C: Tonnes of A that
are foreign-owned
D: Tonnes owned
by a country (A+B-C)
Britian54.80.93.851.9
France65.40.230.035.6
Belgium2.7~ 0.8 (b)~ 2 (b)~ 1.5
Germany4.9not declared (c)not declared~ 21 (c)
Japan5.015.1020.1
Switzerland0.1 to 0.150 to 6 (d)0.1~ 1
Russia28.1not declarednot declared28.1
United States (e)5005
China0000
India (f)0.5000.5
Netherlands (g)0~ 1.5 ? 0~ 1.5
Italy (h)0 ?~ 0.5 ?0~ 0.5
TOTAL166.5166.7

Table 2 (con’t): Separated Civil Plutonium 1997

(a) Unless otherwise noted, the source of this information is the IAEA’s INFCIRC/549 and its associated declarations; ISIS estimates are in italics. The totals of Columns A and D do not match because either the declarations are incomplete or the plutonium in Column B is in a country not listed. Although not listed here, Sweden has both reprocessing contracts and plans to use MOX fuel in its reactors.
(b) Belgian holdings in other countries were not declared in 1996, but they are approximately the quantity declared in 1997. The estimate of 2 tonnes of foreign-owned plutonium is based on discussions with Belgian nuclear officials.
(c) German holdings in other countries are estimated by assuming that this material is held in Britain, France or Belgium and that the vast bulk of Belgian, German, Japanese, Swiss, Dutch and Italian holdings outside of their countries (Column B) is equal to the amount of plutonium in Britain, France and Belgium that is foreign-owned. Central estimate for 1996 is 16 tonnes.
(d) Six tonnes of plutonium in spent fuel was sent for reprocessing according to Switzerland’s declaration to the IAEA. Most of this plutonium is not separated.
(e) ISIS estimate of the amount of unirradiated plutonium originally produced in civil reactors that is part of the 52.5 tonnes declared excess by the US.
(f) ISIS estimate.
(g) ISIS estimate; and information from Tom Clements. All or almost all Dutch separated plutonium is located in France.
(h) Estimate of Italian plutonium stored in Britain. ISIS does not know if Italy has an in-country stock of a few hundred kilograms of separated plutonium. It is assumed that Italian plutonium in Superphenix fuel is irradiated; if not, or if a swap happened, then the values in Column B and Column D could increase by a few tonnes.

Table 2: Key Unirradiated Civil Plutonium Inventories (con’t)

Separated Civil Plutonium 1997 (in tonnes) (a)

A: Holdings
in-country
B: Holdings in
other countries
C: Tonnes of A that
are foreign-owned
D: Tonnes owned
by a country (A+B-C)
Britian60.10.96.154.9
France72.3less than 0.0533.638.7
Belgium2.80.8~ 2 (b)~ 1.6
Germany6.0not declared (c)not declared~ 24 (c)
Japan5.019.1024.1
Switzerland0.70 to 5 (i)less than 0.05~ 1
Russia (j)29.1not declarednot declared29.1
United States (e)5005
China (k)0000
India (f)0.6000.6
Netherlands (g)0~ 1.5 ? 0~ 1.5
Italy (h)0 ?~ 0.5 ?0~ 0.5
TOTAL181.6181.0

BACK

(a) Unless otherwise noted, the source of this information is the IAEA’s INFCIRC/549 and its associated declarations; ISIS estimates are in italics. The totals of Columns A and D do not match because either the declarations are incomplete or the plutonium in Column B is in a country not listed. Although not listed here, Sweden has both reprocessing contracts and plans to use MOX fuel in its reactors.
(b) Belgian holdings in other countries were not declared in 1996, but they are approximately the quantity declared in 1997. The estimate of 2 tonnes of foreign-owned plutonium is based on discussions with Belgian nuclear officials.
(c) German holdings in other countries are estimated by assuming that this material is held in Britain, France or Belgium and that the vast bulk of Belgian, German, Japanese, Swiss, Dutch and Italian holdings outside of their countries (Column B) is equal to the amount of plutonium in Britain, France and Belgium that is foreign-owned. Central estimate for 1997 is 18 tonnes.
(e) ISIS estimate of the amount of unirradiated plutonium originally produced in civil reactors that is part of the 52.5 tonnes declared excess by the US.
(f) ISIS estimate.
(g) ISIS estimate; and information from Tom Clements. All or almost all Dutch separated plutonium is located in France.
(h) Estimate of Italian plutonium stored in Britain. ISIS does not know if Italy has an in-country stock of a few hundred kilograms of separated plutonium. It is assumed that Italian plutonium in Superphenix fuel is irradiated; if not, or if a swap happened, then the values in Column B and Column D could increase by a few tonnes.
(i) Five tonnes of plutonium in spent fuel was sent for reprocessing according to Switzerland’s declaration to the IAEA. Most of this plutonium is not separated.
(j) The Russian inventory is estimated to increase by one tonne from the 1996 declaration. There is no Russian declaration for 1997 but the Russian inventory at the end of 1998 was declared as 30.3 tonnes.
(k) Not yet declared but assumed to be the same as the 1996 declaration.

Table A1: Cumulative Plutonium Discharges from
Civilian Nuclear Power Reactors (in tonnes) (a)

Plutonium Discharges
 End of 1997End of 1998
Argentina8.38.8
Armenia3.23.2
Belgium2022
Brazil0.70.8
Bulgaria9.510
Canada9397
China0.91.3
Czech Republic4.65.1
Finland1112
France156170
Germany7883
Hungary5.66.2
India6.57.4
Italy5.75.7
Japan112120
South Korea2326
Lithuania6.36.5
Mexico1.01.3
Netherlands2.82.9
Pakistan0.50.6
Romania0.30.7
Russia7882
Slovakia6.16.5
Slovenia2.02.1
South Africa3.74.2
Spain2527
Sweden3133
Switzerland1516
Taiwan1516
Ukraine2729
United Kingdom7578
United States289304
TOTAL1,1161,188

BACK

(a) Spent fuel and plutonium discharges through 1993 are calculated in David Albright, Frans Berkhout, and William Walker, Plutonium and Highly Enriched Uranium 1996, World Inventories, Capabilities and Policies (Oxford:Stockholm International Peace Research Institute and Oxford University Press, 1997). Spent fuel from 1994 through 1998 was calculated following the methodology detailed in Appendix B of Plutonium and Highly Enriched Uranium 1996. For spent fuel in LWRs we modified this method by subtracting 1/6th of a core of fuel from each reactor to compensate for uncertainty in the fuel unloading schedule. Plutonium from 1994 through 1998 was calculated following the methodology detailed in Appendix B of Plutonium and Highly Enriched Uranium 1996. The uncertainty in these estimates is 10 to 20%. An exception is the United States, which declared 274.4 tonnes of plutonium in spent fuel in 1996 and so the uncertainty in the US estimates is less than 10%. Additionally, Canada has declared its discharges of spent nuclear fuel, which corroborated these estimates. These estimates do not include reactor cores, which contain about 100 tonnes of plutonium. And, these estimates have not been corrected for the decay of plutonium 241 into americium 241, nor have they been corrected for plutonium inserted into reactors in the form of MOX fuel and subsequently fissioned.

Table A2: Civil Plutonium Inventory, corrected (in tonnes) (a)

  End of 1997 End of 1998
Plutonium produced1,1161,188
Correction for plutonium 241 decay(42)(45)
Correction for use of MOX fuel in LWRs(25)(30)
TOTAL1,0491,113

BACK

(a) The methodology used to calculate plutonium discharges for Table A1 makes several simplifying assumptions. Corrections account for two factors that lead to overestimates in the plutonium inventory. The first reduces the total inventory by the amount of plutonium 241 that has decayed. The second correction accounts for the reduction in plutonium, based on an estimate of the total amount of separated plutonium irradiated as MOX fuel in LWRs. The calculation of the amount of plutonium in discharged fuel (Table A1) assumes that all the LWR fuel is enriched uranium; this calculation does not account for the amount of separated plutonium initially inserted into a reactor in the form of MOX fuel and subsequently fissioned in the reactor. Breeder reactors are ignored here.

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